Tag: gas laws and mole concept

Questions Related to gas laws and mole concept

If the yield of chloroform obtainable from acetone and bleaching powder is $75\%$, what mass of acetone is require for producing $30\ g$ of chloroform? 

  1. $40\ g$

  2. $9.4\ g$

  3. $10.92\ g$

  4. $14.56\ g$


Correct Option: A

1 mole of a compound contains 1 mole of C and 2 moles of O. The molecular weight of the compound is:

  1. 3

  2. 12

  3. 32

  4. 44


Correct Option: D
Explanation:

As 1 mole of a compound contains 1 mole of C and 2 moles of O. 


$ CO _2 \rightarrow12 + 2\times 16= 12 +32 \rightarrow 44 g $

Option D is correct.

What is the weight of $3$ gram atoms of sulphur?

  1. $96 g$

  2. $99 g$

  3. $100 g$

  4. $3 g$


Correct Option: A
Explanation:

 The atomic mass of sulphur is 32 g / g atom. The weight of 3 gram atoms of sulphur is $3 \text { g atom } \times 32 \text { g / g atom } =96$ g.

Iron pyrites has formula $FeS _2. (Fe = 56; S = 32)$. What is the mass of sulfur contained in 30 grams of pyrites?

  1. 16 g

  2. 32 g

  3. 20 g

  4. 24 g


Correct Option: A
Explanation:

Molecular weight of $ \displaystyle FeS _2 =  56+2(32)=120$ g/mol.

One mole (120 g) of $ \displaystyle FeS _2$ will contain $ \displaystyle 2 \times 32 = 64$ g of $S$
30 g of $ \displaystyle FeS _2$ will contain $ \displaystyle \dfrac {30}{120} \times  64=16$ g of $S$.
Hence, the mass of sulfur contained in 30 grams of pyrites is 16 g.

An organic compound contains 69% carbon, 4.8% hydrogen and the remaining is oxygen. calculate the masses of carbon dioxide produced when 0.20g of substance is subjected to combustion.
  1. 0.40 g

  2. 0.50 g

  3. 0.60 g
  4. 0.70 g


Correct Option: B
Explanation:
Percentage of carbon in organic compound $= 69 \%$

So, 100 g of organic compound contains 69 g of carbon.

∴ 0.2 g of organic compound will contain $=\dfrac{ 69 \times 0.2}{ 100} = 0.138$ g of carbon

The molecular mass of carbon dioxide, $CO _2 = 44$ g

So, 12 g of carbon is contained in 44 g of $CO _2$.

0.138 g of carbon will be contained $= \dfrac{44 \times 0.138}{12} = 0.506$ g of carbon.

Thus, 0.506 g of $CO _2$ will be produced on complete combustion of 0.2 g of an organic compound.

The mass of one molecule of water is approximately:

  1. $1\ g$

  2. $0.5\ g$

  3. $1.66 \times 10^{-24}\, g $

  4. $ 3 \times 10^{-23}\, g $


Correct Option: D
Explanation:
Mass of $6.0 \times 10^{23}$ molecules of water is 18 g.

Mass of 1 molecule of water $=\dfrac{M}{N _A}=\dfrac{18}{6.0\times 10^{23}}$

Mass of 1 molecule of water $=3. \times$ $10^{-23}$ g 

In an experiment, the following four gases were produced. 11.2 L of which two gases at STP will weigh 14 g ?

  1. $N _2O$

  2. $NO _2$

  3. $N _2$

  4. $CO$


Correct Option: C,D
Explanation:
22.4 L of  a gas at STP$=$ 1 mole.
11.2 L of  a gas at STP$=$ 0.5 mole.
11.2 L of a gas at STP will weigh 14 g.
0.5 moles of a gas at STP will weigh 14 g.
1 mole of a gas at STP will weigh $\dfrac {1}{0.5} \times 14=28$ g.
The molecular weight of the gas is 28 g/mol.
Molecular weight of  $N _2O = 2 (14)+16=44$ g/mol.
Molecular weight of  $NO _2 =14+ 2 (16)=46$ g/mol.
Molecular weight of  $N _2 = 2 (14)=28$ g/mol.
Molecular weight of  $CO = 12+16=28$ g/mol.
Hence, 11.2 L of $N _2$ and $CO$ at STP will weigh 14 g.

If of conservation of mass was to hold true, then 20.8 g of ${ BaCl } _{ 2 }$ on reaction with 9.8 g of ${ H } _{ 2 }{ SO } _{ 4 }$ will produce 7.3 g of $HCl$ and ${ BaSO } _{ 4 }$ equal to :

  1. 11.65 g

  2. 23.3 g

  3. 25.5 g

  4. 30.6 g


Correct Option: B
Explanation:

$BaCl _2+H _2SO _4 \longrightarrow BaSO _4+2HCl$


$1$ mole of $BaCl _2$ reacts with $1$ mole of $H _2SO _4$ to give $1$ mole of $BaSO _4$ and $2$ moles of $HCl$.


Here, moles of $BaCl _2=\dfrac{20.8}{208}=$ moles of $H _2SO _4= \dfrac{9.8}{98}=0.1$

$\therefore$ Moles of $BaSO _4$ formed $=0.1$

$\therefore$ Mass of $BaSO _4$ formed $=0.1 \times 233= 23.3 g$


i.e. $20.8+9.8=7.3+23.3=30.6$

Hence the correct option is B.

The number of electrons which will together weigh one gram is :

  1. $1.098 \times 10^{27}$ electrons

  2. $9.1096\times 10^{31}$ electrons

  3. 1 electrons

  4. $1\times 10^4$ electrons


Correct Option: A
Explanation:

Mass of a electrons = $9.1096\times 10^{-31}Kg$
1g or $10^{-3}kg = \dfrac{1}{9.1096\times 10^{-31}}\times 10^{-3}$
=$1.098\times 10^{27}$ electons

What is the mass of oxalic acid, $ H _{2}C _{2}O _{4},$ which can be oxidized to $ CO _{2}$ by 100 ml of $MnO _{4}^{-}$ solution, 10 ml of which is capable of oxidizing 50 ml of $ 1.00 N\ I^{-} $ to $ I _{2}?$

  1. 2.25 g

  2. 52.2 g

  3. 25.2 g

  4. 22.5 g


Correct Option: D
Explanation:

Balanced chemical reaction,
$2KMnO _{4}+5H _{2}C _{2}O _{4}+3H _{2}SO _{4}\rightarrow 2MnSO _{4}+10CO _{2}+K _{2}SO _{4}+8H _{2}O$

$(KMnO _{4})N _{1}V _{1}= N _{2}V _{2}(I _{2})$

$N _{1}\times 10= 1\times 50$

$N _{1}= 5N$

n-factor for $KMnO _{4}= 7-2=5$

Moles of $KMnO _{4}=\dfrac{5}{5}=1$

2 mole $KMnO _{4}= 5$ mole $H _{2}C _{2}O _{4}$

1 mole $KMnO _{4}= 2.5$ mole $H _{2}C _{2}O _{4}$

In 100 mL or 0.1 L $= 0.1\times 2.5= 0.25$ moles

Mass of $H _{2}C _{2}O _{4}= 0.25\times 90= 22.5g$