Tag: properties of alkaline earth metals

Questions Related to properties of alkaline earth metals

In which case first has lower melting point than second?

  1. Mg, Be

  2. Be, Ca

  3. Cs, Li

  4. K, Li


Correct Option: A,C,D
Explanation:

(A) The melting point of magnesium is 924 K which is lower than the melting point of beryllium which is 1560 K.
(B) The melting point of beryllium is 1560 K which is higher than the melting point of calcium.
(C) The melting point of cesium is 302 K which is lower than the melting point of lithium which is 454 K.
(D) The melting point of potassium is 336 K which is lower than the melting point of Li which is 454 K.

In which case second has lower boiling point than first?

  1. Li, K

  2. Be, Mg

  3. Li, Cs

  4. Ca, Mg


Correct Option: A,B,C,D
Explanation:

(A) The boiling point of K is $1032$ K which is lower than that of Li ($1615$ K)
(B) The boiling point of Mg is $1363$ K which is lower than that of Be ( $2745$ K).
(C) The boiling point of Cs is $944$ K which is lower than that of Li ($1615$ K).
(D) The boiling point of Mg is $1363$ K is which is lower than that of Ca ($1767$ K).
Hence, all are correct.

The correct sequence of increasing melting point of $BeCl _{2},MgCl _{2},CaCl _{2},SrCl _{2}$ and $BaCl _{2}$ is

  1. $BaCl _{2} < SrCl _{2} < CaCl _{2} < MgCl _{2} < BeCl _{2}$

  2. $BeCl _{2} < MgCl _{2} < CaCl _{2} < SrCl _{2} < BaCl _{2}$

  3. $BeCl _{2} < CaCl _{2} < MgCl _{2} < SrCl _{2} < BaCl _{2}$

  4. $MgCl _{2} < BeCl _{2} < SrCl _{2} < CaCl _{2} < BaCl _{2}$


Correct Option: B

Which of the alkaline earth elements forms covalent bonds ? 

  1. Ca

  2. Mg

  3. Sr

  4. Be


Correct Option: D

Estimation of calcium and magnesium is done by :

  1. EDTA.

  2. oxalate.

  3. phosphate.

  4. None of these.


Correct Option: A
Explanation:

Estimation of calcium and magnesium is done by EDTA in complexometric titration. Hexadentate ligand EDTA (ethylene diammine tetra acetate) forms metal chelates with calcium and magnesium. 

Lightest alkaline earth metal is :

  1. Be

  2. Mg

  3. Ca

  4. Sr


Correct Option: A
Explanation:

Beryllium (Be), is the lightest alkaline earth metal with atomic number 4 and mass number 9.

Flame test is not given by :

  1. Ca

  2. Ba

  3. Be

  4. Li


Correct Option: C
Explanation:

Beryllium and magnesium do not give any colour to the flame test because they have a small size and very high ionization enthalpies. The energy of the flame is not sufficient to excite the electrons to higher energy levels. Hence, they do not impart any characteristic colour to the flame.

Hence option B is correct.

The first ionization energies of alkaline earth metals are higher than those of the alkali metals. This is because:

  1. there is increase in the nuclear charge of the alkaline earth metal

  2. there is decrease in the nuclear charge of the alkaline earth metal

  3. there is no change in the nuclear charge

  4. none ofthe above


Correct Option: A
Explanation:

As the nuclear charge increases it requires more energy to remove electron(Ionization energy) hence ionization energy will be increased. The first ionization energies of alkaline earth metals are higher than those of the alkali metals. This is because of the increase in the nuclear charge of the alkaline earth metal.

Alkaline earth metal salt are :

  1. paramagnetic

  2. diamagnetic

  3. ferromagnetic

  4. all of these


Correct Option: B
Explanation:

Alkali earth metals are diamagnetic.

Atoms or elements which are having even number of electrons or  no unpaired electrons are diamagnetic.

Alkaline earth metals are having even number of electrons(Be,Mg,Ca,Sr,Ba,Ra having electrons 4,12,20,38,56 and 88 respectively which are even in number)

Hence option B is correct